Table 3 The mechanism for formaldehyde oxidation.
Reaction | Rate constants |
|---|---|
HCO + O2 → HO2 + CO | 6.02 × 1010 |
HO2 + CH2O → H2O2 + HCO | 3.43 × 1010 |
H2O2 + M → 2OH + M | 4.01 × 106 |
OH + CH2O → H2O + HCO | 9.64 × 1013 |
OH + H2O2 → H2O + HO2 | 3.07 × 1012 |
H2O2 → H2O2(wall) | 1.05 × 102 |
HO2 → HO2(wall) | 1.05 × 101 |
HO2 + HO2 → H2O2 + O2 | 1.81 × 1012 |
OH + CO → CO2 + H | 1.99 × 1011 |
HO2 + CO → CO2 + OH | 7.23 × 108 |
H + CH2O → H2 + HCO | 1.63 × 1012 |
H + O2 → OH + O | 3.32 × 1010 |
H + O2 + M → HO2 + M | 3.63 × 1015 |
HO2 + M → H + O2 + M | 2.83 × 105 |
O + H2 → OH + H | 1.82 × 1011 |
O + CH2O → OH + HCO | 6.02 × 1013 |
H + H2O2 → HO2 + H2 | 7.83 × 1011 |
H + H2O2 → H2O + OH | 3.55 × 1012 |
O + H2O2 → OH + HO2 | 6.02 × 1010 |
HCO → H + CO | 4.60 × 10-12 |
OH + H2 → H2O + H | 6.02 × 1012 |
CH2O + O2 → HCO + HO2 | 1.75 × 104 |
H + HO2 → 2OH | 3.01 × 1012 |
H + HO2 → H2O + O | 3.01 × 1013 |
H + HO2 → H2 + O2 | 2.71 × 1013 |