Table 4 Sensitivity coefficients for formaldehyde oxidation.
Rate constant | ∂ ln [HO2]/∂k i | ∂ ln [O]/∂k i | ||||
|---|---|---|---|---|---|---|
| Â | IDM | R/DM | our algorithm | IDM | R/DM | our algorithm |
k 2 | 0.683 | 0.683 | 0.68255 | 0.827 | 0.827 | 0.82719 |
k 3 | 0.700 | 0.700 | 0.69986 | 0.835 | 0.835 | 0.83486 |
k 4 | -0.210 | -0.209 | -0.20917 | -1.160 | -1.156 | -1.15579 |
k 8 | -0.306 | -0.306 | -0.30569 | -0.296 | -0.296 | -0.29599 |
k 9 | 0.210 | 0.210 | 0.20962 | 1.156 | 1.156 | 1.15628 |
k 10 | 0.164 | 0.164 | 0.16373 | 1.031 | 1.031 | 1.03065 |
k 11 | -0.121 | -0.121 | -0.12087 | -0.660 | -0.659 | -0.65906 |
k 12 | 0.188 | 0.188 | 0.18848 | 0.979 | 0.979 | 0.97926 |
k 13 | Â | Â | Â | -0.327 | -0.327 | -0.32713 |
k 16 | Â | Â | Â | -1.002 | -1.000 | -0.99990 |
k 22 | 0.686 | 0.685 | 0.68536 | 0.742 | 0.742 | 0.74169 |